"I'm deeply disappointed that the only country in the EU that could not accept a good compromise on how we can move Europe to a low carbon economy was Poland," said UK Energy and Climate Change Secretary Chris Huhne.
The EU is committed to a 20% cut in CO2 emissions by 2020, from 1990 levels.
But there are now calls for a 30% cut.
EU environment ministers discussed a European Commission roadmap to 2050 on climate and energy, which sets out how the EU can move to a competitive low-carbon economy and cut CO2 emissions.
But there was no agreement to set more ambitious CO2 targets at the talks in Luxembourg on Tuesday.
Poland is poised to gain more influence over EU negotiations when it takes over the rotating six-month EU presidency on 1 July. Read the full report here.
Source: BBC News, UK.